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Microstructure and Adhesion Properties Post-Annealed Metallic Coating of Fecrbmnsi on Tube and Internal Structure Coal-Fired Boiler

机译:Fecrbmnsi在管和内部结构燃煤锅炉上的退火后金属涂层的微观结构和粘附性能

摘要

Iron-chrome based metallic coating is generally used to increase the life-time tube and internal structure of coal-fired boiler. The most common method used is thermal spray coating. The advantages of this method are simple in application, repair, and low cost. The post-heat treatment coating on metallic coating applied by the thermal spray method can affect to adhesion properties, the number of porosity and microstructure of coating material. The objective of this study is to analyze the influence of post-annealing on the metallic coating FeCrBMnSi applied by Twin Wire Arc-Spraying (TWAS) method on microstructure and adhesion properties which is applied on tube and internal structure of coal-fired boiler. Post-annealing was performed after coating application in vacuum furnace with variety of temperature at 500oC, 600oC and 700o and holding time about 3 hours. Scanning Electron Microscopy (SEM) and Energy Dispersive X-Ray Spectroscopy (EDS) were used to analyze the morphology of microstructure, the uniformity of the deposit layer, and the percentage of porosity. X- Ray Diffraction (XRD) was used to determine phase formation and composition phase. Then, Pull Off Test was performed for adhesion test that is referred to ASTM D4541. The results shows that increasing post-annealed temperature cause microstructure of coating more crystalline, percentage of porosity decreased from 3% As-sprayed to 1,4% at 700oC post-annealing temperature and it has an effect on the adhesion properties of coating which increase up to 25%.
机译:铁铬基金属涂层通常用于增加燃煤锅炉的使用寿命和内部结构。最常用的方法是热喷涂。该方法的优点是应用,维修简单,成本低。通过热喷涂方法在金属涂层上进行的后处理涂层会影响涂层的附着性能,孔隙率和涂层的微观结构。本研究的目的是分析后退火对采用双丝电弧喷涂(TWAS)方法施加的金属涂层FeCrBMnSi的影响,该效应对应用于燃煤锅炉管和内部结构的组织和粘附性能的影响。在真空炉中涂覆涂料后,在500oC,600oC和700o的各种温度下,保持时间约3小时后,进行后退火。扫描电子显微镜(SEM)和能量色散X射线光谱(EDS)用于分析微观结构的形态,沉积层的均匀性和孔隙率。 X射线衍射(XRD)用于确定相形成和组成相。然后,针对ASTM D4541进行附着力测试的拉拔测试。结果表明,退火后温度升高导致涂层的微观结构更加结晶,在退火后700oC时,气孔率从3%的喷涂态降低至1.4%,并且对涂层的附着性能产生影响。高达25%。

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